Publications
Sandford Group Publications
14. Hung, C.-T.; Wu, B.-S.; Chou, C.-T.; Sandford, C.*; Tsai, C.-C.* "Insight into Stereocontrol in the Asymmetric Intramolecular Allylation with a tert-Butylsulfinamide Nucleophile: Application in the Synthesis of Chiral Isoindoline-1-Carboxylic Acid Esters."
Mentored Publications
13. Tang, T.; Sandford, C.; Minteer, S. M.*; Sigman, M. S.* "Analyzing Mechanisms in Co(I) Redox Catalysis Using a Pattern Recognition Platform."
12. Tsai, C.-C.§; Sandford, C.§; Wu, T.; Chen, B.; Sigman, M. S.*; Toste, F. D.* "Enantioselective Intramolecular Allylic Substitution via Synergistic Palladium/Chiral Phosphoric Acid Catalysis: Insight into Stereoinduction through Statistical Modeling."
Angew. Chem. Int. Ed. 2020, 59, 14647–14655.
[§ denotes equal contribution]
11. Barman, K.; Edwards, M. A.; Hickey, D. P.; Sandford, C.; Qiu, Y.; Gao, R.; Minteer, S. D.*; White, H. S.* "Electrochemical Reduction of [Ni(Mebpy)3]2+: Elucidation of the Redox Mechanism by Cyclic Voltammetry and Steady-State Voltammetry in Low Ionic Strength Solutions."
10. Sandford, C.; Fries, L. R.; Ball, T. E.; Minteer, S. D.*; Sigman, M. S.* "Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization."
9. Sandford, C.; Edwards, M. A.; Klunder, K. J.; Hickey, D. P.; Li, M.; Barman, K.; Sigman, M. S.*; White, H. S.*; Minteer, S. D.* "A Synthetic Chemist's Guide to Electroanalytical Tools for Studying Reaction Mechanisms." [Review Article]
Chem. Sci. 2019, 10, 6404–6422.
[Themed collections: "Most popular 2019-2020 review articles", "Most popular 2019-2020 organic chemistry articles", and "Most popular 2018-2019 organic chemistry articles"]
8. Hickey, D. P.§; Sandford, C.§; Rhodes, Z.; Gensch, T.; Fries, L. R.; Sigman, M. S.*; Minteer, S. D.* "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates."
J. Am. Chem. Soc. 2019, 141, 1382–1392.
[One of the top-20 most read articles in JACS in January 2019]
[§ denotes equal contribution]
7. García-Ruiz, C.; Chen, J. L.-Y.; Sandford, C.; Feeney, K.; Lorenzo, P.; Berionni, G.; Mayr, H.; Aggarwal, V. K.* "Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles."
J. Am. Chem. Soc. 2017, 139, 15324–15327.
[One of the top-20 most read articles in JACS in January 2017]
6. Armstrong, R. J.; Sandford, C.; García-Ruiz, C.; Aggarwal, V. K.* "Conjunctive Functionalization of Vinyl Boronate Complexes with Electrophiles: A Diastereoselective Three-Component Coupling."
5. Silvi, M.; Sandford, C.; Aggarwal, V. K.* "Merging Photoredox with 1,2-Metallate Rearrangements: The Photochemical Alkylation of Vinyl Boronate Complexes."
J. Am. Chem. Soc. 2017, 139, 5736–5739.
[Highlighted in Angew. Chem. Int. Ed.]
4. Sandford, C.; Aggarwal, V. K.* "Stereospecific Functionalizations and Transformations of Secondary and Tertiary Boronic Esters." [Review Article]
Chem. Commun. 2017, 53, 5481–5494.
[Themed collections: "Most cited articles from 2017", "Most cited Features from 2016, 2017", and "Most downloaded articles of 2017: Organic and Biological Chemistry"]
3. Wang, Y.; Noble, A.; Sandford, C.; Aggarwal, V. K.* "Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans."
2. Farley, A. J. M.§; Sandford, C.§; Dixon, D. J.* "Bifunctional Iminophosphorane Catalyzed Enantioselective Sulfa-Michael Addition to Unactivated α-Substituted Acrylate Esters."
J. Am. Chem. Soc. 2015, 137, 15992–15995.
[§ denotes equal contribution]
1. Sandford, C.; Rasappan, R.; Aggarwal, V. K.* "Synthesis of Enantioenriched Alkylfluorides by the Fluorination of Boronate Complexes."
J. Am. Chem. Soc. 2015, 137, 10100–10103.
[One of the top-20 most read articles in JACS in August 2015]
